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纸质出版日期： 2024-03-25 ，
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郑军宝，闫英杰，曹睿.时效处理对Fe-Ni基奥氏体合金耐点蚀性能的影响［J］.电焊机，2024，54（3）：18-23.
ZHENG Junbao, YAN Yingjie, CAO Rui.Effect of Aging Treatment on Pitting Corrosion Resistance of Fe-Ni Based Austenitic Alloy[J].Electric Welding Machine, 2024, 54(3): 18-23.
针对Fe-Ni基奥氏体合金在740 ℃时效处理后的析出相随时效时间的演变进行探究；并通过电化学腐蚀试验以及Mott-Schottky分析，研究了时效处理对合金耐腐蚀性能的影响。结果表明：740 ℃时效处理可以促进γ′沉淀强化相［Ni
3
（Al，Ti）］在合金中的析出；随时效时间的增加，γ′析出相的密度和尺寸增加；同时，时效处理会增加合金表面点缺陷数量，降低合金钝化膜致密性，从而导致合金耐点蚀性降低；通过恒电位阳极极化处理能够有效降低合金表面点缺陷数量，提高合金耐点蚀性。
The evolution of precipitated phase of Fe-Ni based austenite alloy after aging at 740 ℃ with aging time was investigated. The effect of aging treatment on corrosion resistance of the alloy was studied by electrochemical corrosion test and Mott-Schottky analysis. The results show that aging treatment at 740 ℃ can promote the precipitation of γ′ phase [Ni
3
(Al
Ti)] in the alloy. The density and size of γ′ precipitated phase increase with aging time. At the same time
aging treatment can increase the number of spot defects on the alloy surface
reduce the density of the alloy passivation film
and lead to the decrease of the pitting resistance of the alloy. Constant potential anodic polarization treatment can effectively reduce the number of point defects on the alloy surface and enhance the alloy’s resistance to pitting corrosion. The self-corrosion current density of the alloy before aging is -6.697 7 A/cm
2
while after aging for 4 hours and 8 hours
it is -5.716 4 A/cm
2
and -6.081 2 A/cm
2
respectively
both higher than before aging. After electrochemical surface modification
the self-corrosion current density of the alloy before aging is -7.490 125 A/cm
2
and after aging for 4 hours and 8 hours
it is -6.127 403 A/cm
2
and -6.486 164 A/cm
2
respectively
still lower than before aging.
Fe-Ni基奥氏体合金时效处理γ′析出相耐点蚀性能表面改性
Fe-Ni based austenitic alloyaging treatmentγ′ precipitated phasepitting resistancesurface modified technique
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