In this study, the brazing experiments of 1Cr12Ni3MoVN stainless steel were carried out using BNi82CrSiB(i.e. BNi-2) filler metal. Microstructure and mechanical property of the brazed joints were analyzed. The results revealed that sound joints could be obtained by using BNi-2 filler metal brazed at brazing temperature of 1 070 ℃ for 15 min. The diffusion treatment at temperature of 940 ℃ for 1 h after brazing at 1 070 ℃ could decrease the width of seam and refine the microstructure. After diffusion treatment, the average tensile strength of the joint was obviously increased up to 382.0 MPa, but the tensile specimen still exhibited brittle fracture mode and the fracture occurred in the brazing seam.