Influence of Alloying Elements on the Microstructure and Properties of Cu-Ni based Fusion Cladding Layers

ZHOU Wenkun; DIAO Jianshuai; ZHANG Min; XUE Tianqi; MA Ke; MAO Wei; MA Hongwei

doi:10.7512/j.issn.1001-2303.2024.11.02

Overlaying and Surface Engineering | Views : 0 下载量: 10 CSCD: 0

PDF
Export
Share
Collection
Album

Influence of Alloying Elements on the Microstructure and Properties of Cu-Ni based Fusion Cladding Layers
Vol. 54, Issue 11, Pages: 9-18(2024)
Published： 25 November 2024 ，
DOI： 10.7512/j.issn.1001-2303.2024.11.02
稿件说明：

移动端阅览

周文坤，刁健帅，张敏，等.合金元素对Cu-Ni基熔覆层组织和性能的影响［J］.电焊机，2024，54（11）：9-18.

ZHOU Wenkun, DIAO Jianshuai, ZHANG Min, et al.Influence of Alloying Elements on the Microstructure and Properties of Cu-Ni based Fusion Cladding Layers[J].Electric Welding Machine, 2024, 54(11): 9-18.
周文坤，刁健帅，张敏，等.合金元素对Cu-Ni基熔覆层组织和性能的影响［J］.电焊机，2024，54（11）：9-18. DOI： 10.7512/j.issn.1001-2303.2024.11.02.

ZHOU Wenkun, DIAO Jianshuai, ZHANG Min, et al.Influence of Alloying Elements on the Microstructure and Properties of Cu-Ni based Fusion Cladding Layers[J].Electric Welding Machine, 2024, 54(11): 9-18. DOI： 10.7512/j.issn.1001-2303.2024.11.02.

摘要

为改善高强钢的表面性能，利用电弧熔覆技术在X80钢表面制备了两种添加不同合金的铜基熔覆层，分别为Cu-Ni-Fe-Nb-W和Cu-Ni-Fe-Ti。采用OM、SEM、EDS、显微硬度计、摩擦磨损试验机以及电化学工作站等仪器设备研究了Nb-W、Ti等合金元素对Cu-Ni基熔覆层组织和性能的影响。结果表明，两组Cu-Ni基熔覆层的显微组织由底部到顶部均为平面晶、胞状晶、树枝晶和等轴晶，Nb-W和Ti均有细化Cu-Ni熔覆层组织的作用。Cu-Ni-Fe-Nb-W熔覆层的平均硬度值为161.9 HV0.1，Cu-Ni-Fe-Ti熔覆层的平均硬度值为176.4 HV0.1，且Cu-Ni-Fe-Ti熔覆层的摩擦系数和磨损量均低于Cu-Ni-Fe-Nb-W熔覆层，表明添加Nb-W和Ti能够提升熔覆层的力学性能，且添加Ti元素的效果要优于Nb-W元素。电化学测试表明，添加合金元素的Cu-Ni基熔覆层的耐蚀性要明显优于X80钢的耐蚀性，且Cu-Ni-Fe-Ti熔覆层的耐蚀性优于Cu-Ni-Fe-Nb-W熔覆层。

Abstract

To improve the surface properties of high-strength steel

two types of copper-based cladding layers with different added alloys were prepared on the surface of X80 steel using arc cladding technology

namely Cu-Ni-Fe-Nb-W and Cu-Ni-Fe-Ti. The effects of Nb-W and Ti alloy elements on the microstructure and properties of Cu-Ni-based cladding layers were studied using instruments such as OM

SEM

EDS

microhardness tester

friction and wear tester

and electrochemical workstation. The results show that the microstructure of the two groups of Cu-Ni-based cladding layers from bottom to top are planar crystals

cellular crystals

dendritic crystals

and equiaxed crystals

and both Nb-W and Ti have the effect of refining the Cu-Ni cladding layer structure. The average hardness value of the Cu-Ni-Fe-Nb-W cladding layer is 161.9 HV0.1

and the average hardness value of the Cu-Ni-Fe-Ti cladding layer is 176.4 HV0.1. The friction coefficient and wear amount of the Cu-Ni-Fe-Ti cladding layer are lower than those of the Cu-Ni-Fe-Nb-W cladding layer

indicating that the addition of Nb-W and Ti can improve the mechanical properties of the cladding layer

and the effect of adding Ti element is better than that of Nb-W element. Electrochemical tests show that the corrosion resistance of the Cu-Ni-based cladding layer with added alloy elements is significantly better than that of X80 steel

and the corrosion resistance of the Cu-Ni-Fe-Ti cladding layer is better than that of the Cu-Ni-Fe-Nb-W cladding layer.

关键词

Cu-Ni基熔覆层合金元素组织力学性能耐蚀性

Keywords

Cu-Ni based cladding layeralloy elementsmicrostructuremechanical propertiescorrosion resistance

references

Arzaghi E，Chia B H，Mohammad M A，et al. Pitting corrosion modelling of X80 steel utilized in offshore petroleum pipelines［J］. Transactions of The Institution of Chemical Engineers.Process Safety and Environmental Protection，Part B，2020，141（1）：135-139.

Zhao S，He L X，Fan X X，et al. Microstructure and chloride corrosion property of nanocrystalline AlTiCrNiTa high entropy alloy coating on X80 pipeline steel［J］. Surface & Coatings Technology， 2019， 375： 215- 220.

Ning J，Yu Z S，Sun K，et al. Comparison of microstructures and properties of X80 pipeline steel additively manufactured based on laser welding with filler wire and cold metal transfer［J］. Journal of Materials Research and Technology，2020，10：1796.

马刚，顾艳红，赵杰，等. X80钢表面Ni涂层在饱和CO2模拟海水中的耐蚀性能［J］. 材料保护，2020，53（08）：9-18.

MA G，GU Y，ZhAO J，et al. Corrosion resistance of Ni coating on X80 steel surface in saturated CO2 simulated seawater［J］. Material Protection，2020，53（08）：9-18.

Tian B R，Cheng Y F. Electrolytic deposition of Ni-Co-Al 2O 3 composite coating on pipe steel for corrosion/erosion resistance in oil sand slurry［J］. Electrochimica Acta，2007，53（2）：511-517.

Wang Q Y，Wang X Z，Luo H，et al. A study on corrosion behaviors of Ni-Cr-Mo laser coating，316 stainless steel and X70 steel in simulated solutions with H2S and CO2［J］. Surface & Coatings Technology，2016，291：250-257.

徐林，胡强，刘俊伟，等. 海洋环境用含Ni耐蚀铜合金研究现状及展望［J］. 铜业工程，2022，178（06）：1-6.

XU L，HU Q，LIU J W，et al. Research status and prospects of Ni containing corrosion-resistant copper alloys for marine environments［J］.Copper Engineering，2022，178（06）：1-6.

Wu Q L，Zhang J Q. Corrosion behavior of laser-clad Cu-9Ni-6Sn coating［J］. Surface and Coatings Technology，2018，349：1117-1129.

Bhattacharya S，Dinda G P，Dasgupta A K，et al. Microstructural evolution and mechanical， and corrosion property evaluation of Cu-30Ni alloy formed by Direct Metal Deposition process［J］. Journal of Alloys & Compounds，2011，509（22）：6364-6373.

张云龙. 铜/钢复合结构增材制造界面调控及过渡材料研究［D］. 陕西：西安理工大学，2021.

ZhANG Y L. Research on Interface Control and Transition Materials in Additive Manufacturing of Copper/Steel Composite Structures［D］. Shanxi：Xi'an University of Technology，2021.

李继红，张云龙，杜明科，等. 合金元素对铜/钢接头连接机理及性能的影响［J］.焊接学报，2021，42（3）：34-41.

LI J H，ZHANG Y L，DU M K，et al. The Influence of Alloy Elements on the Connection Mechanism and Properties of Copper/Steel Joints［J］. Journal of Welding，2021，42（3）：34-41.

Goodarzi D M，Pekkarinen J，Salminen A. Analysis of laser cladding process parameter influence on the clad bead geometry［J］. Welding in the World，2017，61（2）：1-9.

Zhang M，Zhang Y，Du M，et al. Experimental Characterization and Microstructural Evaluation of Silicon

Bronze-Alloy Steel Bimetallic Structures by Additive Manufacturing［J］.Metallurgical and Materials Transactions A，2021，52（10）：4664-4674.

孙海影，高文嫱，陈华，等. 铜基刹车摩擦片的制备及性能研究［J］. 粉末冶金工业，2023，33（04）：49-53.

SUN H Y，GAO W Y，CHEN H，et al. Preparation and Performance Study of Copper based Brake Friction Plates ［J］. Powder Metallurgy Industry，2023，33（04）：49-53.

史晓冉. 等离子喷涂CuNiIn涂层制备及微动摩擦磨损性能研究［D］. 河北：燕山大学，2022.

SHI X R. Preparation and Study on Micro Friction and Wear Properties of CuNiIn Coating by Plasma Spraying ［D］. Hebei：Yanshan University，2022.

Lv Y T，Lang X W，Zhang Q，et al. Study on corrosion behavior of （CuZnMnNi）（100-x）Sn-x high-entropy brass alloy in 5 wt% NaCl solution［J］. Journal of Alloys and Compounds：An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics，2022，921：166051.

Da Silva F S，Cinca N，Dosta S，et al. Corrosion resistance and antibacterial properties of copper coating deposited by cold gas spray［J］. Surface & Coatings Technology，2019，361：292-301.

Milosev I，Kosec T，Strehblow H. XPS and EIS study of the passive film formed on orthopaedic Ti-6Al-7Nb alloy in Hank's physiological solution［J］. Electrochimica Acta，2008，53（9）：3547-3558.

Alert me when the article has been cited

提交

暂无数据